Geochronology, Fluid Inclusions and Isotopic Characteristics of the Dongjun Pb-Zn-Ag Deposit, Inner Mongolia, NE China     

XIE Wei  WEN Shouqin  ZHANG Guangliang  TANG Tieqiao 《《地质学报》英文版》2021,95(5):1611-1633

The Dongjun Pb-Zn-Ag deposit in the northern part of the Great Xing’an Range (NE China) consists of quartz-sulfide vein-type and breccia-type mineralization, related to granite porphyry. Hydrothermal alteration is well-developed and includes potassic-silicic-sericitic alteration, phyllic alteration and propylitic alteration. Three stages of mineralization are recognized on the basis of field evidence and petrographic observation, demarcated by assemblages of quartz-pyrite-arsenopyrite (early stage), quartz-polymetallic sulfide (intermediate stage) and quartz-carbonate-pyrite (late stage). Zircon LA-ICP-MS U-Pb dating indicates that the granite porphyry was emplaced at 146.7 ± 1.2 Ma (Late Jurassic). Microthermometry and laser Raman spectroscopy shows that ore minerals were deposited in conditions of intermediate temperatures (175–359°C), low salinity (0.5–9.3 wt% NaCl eqv.) and low density (0.60–0.91 g/cm3). Ore-forming fluids were derived largely from magmatic hydrothermal processes, with late-stage addition of meteoric water, belonging to a H2O-NaCl-CO2 ± CH4 system. The δ34SV-CDT values range from 0.75‰ to 4.70‰. The 206Pb/204Pb, 207Pb/204Pb, and 208Pb/204Pb values of the ore minerals are in the ranges of 18.240–18.371, 15.542–15.570, and 38.100–38.178, respectively. Data for the S and Pb isotopic systems indicate that the ore-forming metals and sulfur were derived from Mesozoic magma. Based on the geological characteristics and geochemical signatures documented in this study, we conclude that the Dongjun deposit is a mesothermal magmatic hydrothermal vein-type Pb-Zn-Ag deposit controlled by fractures and related to granite porphyry, in response to Late Jurassic tectonic–magmatic–hydrothermal activity. We further conclude that fluid immiscibility, fluid mixing and fluid-rock interactions were the dominant mechanisms for deposition of the ore-forming materials.  相似文献   

Fracture Characteristics and Heat Accumulation of Jixianian Carbonate Reservoirs in the Rongcheng Geothermal Field, Xiong’an New Area     

WANG Yingjin  MA Feng  XIE Heping  WANG Guiling  WANG Zhihe 《《地质学报》英文版》2021,95(6):1902-1914

Geothermal energy plays an important role in urban construction of the Xiong’an New Area. Geothermal reservoir fracture distribution of the Mesoproterozoic Jixianian Wumishan Formation (Fm.) carbonate reservoir in the Rongcheng geothermal field are evaluated based on FMI log from Wells D19 and D21. The results show carbonate reservoir fracture density of Well D19 is 15.2/100 m, greater than that of Well D21 with a value of 9.2/100 m. Reservoir porosity and permeability of Well D19 are better than that of Well D21, and the water saturation is bimodally distributed. The movable fluid volume ratio (BVM) of Well D19 is 2% to 8% with some zones exceeding 20%, while the value of Well D21 is less than 4%. Therefore, reservoir fractures in Well D19 are more conducive to fluid flow. Reservoir fractures have a similar occurrence to normal faults, indicating that the tensile stress field controlled the formation of such fractures. Developed reservoir fractures provide a good channel for groundwater convection. The circulation of regional groundwater and the heat exchange between water and rock and the multiple heat accumulation patterns form a stable and high potential heat reservoir in the Rongcheng geothermal field.  相似文献   

Distribution Prediction of Middle-deep Lacustrine Source Rocks in Eocene Wenchang Formation in the Kaiping Sag,Pearl Mouth Basin     

XIONG Lianqiao  XIE Xiaojun  ZHAO Zhao  ZHANG Chunyu  WANG Long  LIAO Jihu  CAI Lulu  XU Wei 《《地质学报》英文版》2021,95(1):248-258

Oil and gas shows are rich in drilling wells in Kaiping sag,however,large oilfield was still not found in this area.For a long time,it is thought that source rocks were developed in the middle-deep lacustrine facies in the Eocene Wenchang Formation,while there is no source rocks that in middle-deep lacustrine facies have been found in well.Thickness of Wenchang Formation is big and reservoirs with good properties could be found in this formation.Distribution and scale of source rock are significant for further direction of petroleum exploration.Distribution characterization of middle-deep lacustrine facies is the base for source rock research.Based on the sedimentary background,fault activity rate,seismic response features,and seismic attributes were analyzed.No limited classification method and multi-attributes neural network deep learning method were used for predicting of source rock distribution in Wenchang Formation.It is found that during the deposition of lower Wenchang Formation,activity rate of main fault controlling the sub sag sedimentation was bigger than 100 m/Ma,which formed development background for middle-deep lacustrine facies.Compared with the seismic response of middle-deep lacustrine source rocks developed in Zhu I depression,those in Kaiping sag are characterized in low frequency and good continuity.Through RGB frequency decomposition,areas with low frequency are main distribution parts for middle-deep lacustrine facies.Dominant frequency,instantaneous frequency,and coherency attributes of seismic could be used in no limited classification method for further identification of middle-deep lacustrine facies.Based on the limitation of geology knowledge,multi-attributes of seismic were analyzed through neural network deep learning method.Distribution of middle-deep lacustrine facies in the fourth member of Wenchang Formation is oriented from west to east and is the largest.Square of the middle-deep lacustrine facies in that member is 154 km²and the volume is 50 km³.Achievements could be bases for hydrocarbon accumulation study and for exploration target optimization in Kaiping sag.  相似文献   

渤海海域埕岛低凸起东部南区新生代断裂系统及油气分布的控制作用     

谢宗奎  王志伟  明玉坤  王明  张在振  杨彬  马自超  孙士杰  黄元俊 《地学前缘》2021,28(5):413-420

埕岛低凸起东部南区新生代受控于伸展与走滑作用,断裂构造复杂,传统认为中深层北东向与近东西向断层属于同期同沉积断层。针对这一观点及引起的问题,利用钻井和地震资料,运用构造地质理论解析断裂系统。研究区主要发育正断层、走滑正断层两种类型,断开层位有基底—东营组、平原组—东营组、平原组—基底三种情况,现今断裂以东营组与馆陶组之间的区域不整合面为时限划分为两期断裂系统。早期断裂主要切开基底—东下段,属于同沉积断层;晚期断裂主要切开平原组—东营组,可断达基底,其发育受早期断裂制约。北东向与近东西向断层分别属于早晚两期断裂系统,对油气分布各起关键性控制作用:先期基底升降引起的伸展作用形成北东向断层,控制洼槽地貌与深水重力流沉积环境,发育了连片的层状砂质碎屑流;后期郯庐断裂右行走滑派生了近东西向雁列断层,断层面既充当储层上倾方向的遮挡条件,又在东西向挤压时封闭性变差而变成油气垂向运移通道,断层及断层作用控制了圈闭分布与油气聚集的有序性,自东向西,圈闭及油水界面依次升高且充满度变小,呈全充满、欠充满、半充满等状态。断裂系统研究将地质体置于一定的构造应力场中,分析断层组合的空间排列和交切关系以及断层的力学机制和位移特征等,探究时空演化对油气分布的控制作用。断裂系统研究方法在构造作用叠合区具有适宜性,对该区及类似地区的勘探开发具有现实意义。  相似文献   

广西大瑶山西北地区构造分形与成矿预测     

蒋超  李社宏  付嵩  谢卓麟  廖红为 《地球学报》2021,42(4):514-526

本文针对大瑶山西北地区断层和石英脉热液型矿床丰富的特点,以及该区热液矿床成矿是否存在断裂构造分维临界线.采用较高标度的断裂构造分形分维分析(r=5～0.3125 km),研究矿体产状与矿区断裂产状的关系,结合Fry分析综合预测该区成矿潜力.研究区断裂构造分维值为D=1.6897,南北向断裂构造分维值D=1.2947,北东向断裂构造分维值D=1.4593,东西向断裂构造分维值D=1.0250,北西向断裂构造分维值D=1.2003.我们确定研究区热液矿床成矿存在断裂构造分维临界线,研究区成矿预测分维临界线为D=1.5000～1.8000,铅锌矿成矿预测分维临界线为D=1.6000～1.7400,铜矿成矿预测分维临界线为D=1.5000～1.7000,金矿成矿预测分维临界线为D=1.6400～1.8000,重晶石成矿预测分维临界线为D=1.6000～1.7400.矿体严格受到断裂构造的控制,主要的容矿构造为南北向和北东向断裂构造.综合分析后,我们认为该区铜矿床总体沿北东向分布,金矿沿南北向分布,铅锌矿沿南北向分布.按照矿产分布特征,我们预测了6个成矿靶区.  相似文献   

四川盆地下古生界硅质页岩层系中硅质来源及其对有机质保存的影响初探     

谢小敏  刘伟新  张瀛  赵迪斐  唐友军  申宝剑  李志明 《地质论评》2021,67(1):67020014-67020014

四川盆地下古生界两套硅质页岩层系是其重要的页岩气产层,五峰组—龙马溪组硅质含量与TOC及含气量呈正相关性,暗示硅质矿物对该地区页岩气的生成具有重要意义。但硅质来源复杂,且存在后期硅质流体的注入。因此,本文在总结前人的研究成果基础上,对四川盆地寒武系底部硅质岩系与五峰组—龙马溪组硅质岩系的硅质特征进行了详细的岩石学分析,揭示了3种硅质来源特征：①同沉积无机硅质流体;②生物硅;③后期无机硅质流体。其中寒武系底部以同沉积无机硅质流体与生物硅来源为主,同沉积硅质流体导致有机质快速石化埋藏,有机质内部结构及形态保存较好;五峰组—龙马溪组硅质来源以后期无机硅质流体与生物硅来源为主,有机质在保存过程中受硅质流体的影响很小,有机质腐泥化作用充分,内部结构和形态多数保存较差。该研究初步揭示了两套页岩层系的硅质发育岩石学特征,及其对有机质保存的影响,期望能为四川盆地两套页岩气储层差异性提供新的思路与基础地质数据。  相似文献   

云南个旧西凹蚀变花岗岩型铜-锡多金属矿床萤石地球化学特征及其地质意义     

彭强  江小均  李超  范柱国  魏超  陈耀坤  谢小明  禹华 《矿床地质》2021,40(6):1182-1198

关键金属锡作为全球高科技产业的重要战略性资源,其成矿作用及找矿勘查均是目前国际矿床学领域研究的热点.位于滇东南有色金属成矿带西端的个旧具有全球规模最大的锡矿储量,因其具有独特的成矿条件而备受关注.近年来,在个旧老厂矿田西部凹陷带花岗岩体内部发现中型-大型铜-锡多金属矿体,但对其尚缺乏系统的研究.文章对个旧老厂矿田重点坑道和钻孔开展构造-岩相蚀变特征解析,观察到锡铜矿化主要以石英-电气石-萤石-硫化物-锡石脉的形式产于似斑状蚀变花岗岩中,少量以萤石硫化物形式产于花岗岩与碳酸盐接触带的矽卡岩中.文章对与2种成矿作用相关的萤石开展LA-ICP-MS及ICP-MS微量元素和Sr-Nd同位素分析.结果显示:蚀变花岗岩型脉状萤石∑REE为(7～749)×10-6(LA-ICP-MS)、(45.5～77.4)×10-6(ICP-MS),具有强烈的Eu负异常(δEu=0.01～0.08)和弱Ce负异常(δCe=0.56～0.92),(87Sr/86Sr)i变化于0.70953～0.71147;矽卡岩型萤石∑REE为(27.2～1277.0)×10-6(LA-ICP-MS)、(29.8～161.0)×10-6(ICP-MS),具有显著的Eu负异常(δEu=0.01～0.19)和弱的Ce负异常(δCe=0.44～1.05),(87Sr/86Sr)i变化于0.70870～0.71553.通过综合分析这2类萤石的地球化学特征,认为蚀变花岗岩型脉状萤石与矽卡岩型萤石均形成于氧化向还原过渡的环境,且均为岩浆热液活动的产物.2类萤石为近同期形成,其中矽卡岩型萤石中Ca来源于老卡等粒花岗岩和碳酸盐岩地层,蚀变花岗岩型萤石中Ca主要来源于老卡等粒花岗岩.综上,个旧老厂矿田西部凹陷带的似斑状花岗岩为老卡等粒花岗岩体边部的早阶段岩体,其未提供成矿物质,但提供了流体运移通道和就位空间,晚阶段流体上升侵位在老厂西部凹陷带似斑状花岗岩体内部形成岩浆热液脉型铜-锡多金属矿体.该研究可以为个旧锡矿深部及外围增储和滇东南锡矿带下一步找矿方向提供重要的理论指导.  相似文献   

河北涞源大湾锌钼矿床锆石U-Pb和辉钼矿Re-Os年龄及其地质意义     

田林  张志远  王志敏  丁照月  李天琦  卢鸿鹏  安跃辉  胡华斌  谢桂青 《矿床地质》2021,40(6):1214-1229

大湾斑岩-矽卡岩型锌钼矿床地处太行山北段成矿带中,是该段重要的金属矿床之一.五台群板峪口组和长城系高于庄组为主要赋矿围岩,锌钼矿体主要赋存在流纹斑岩体内及斑岩与围岩接触部位.文章对大湾矿床内2件赋矿流纹斑岩进行LA-ICP-MS锆石U-Pb年代测定,获得206Pb/238U年龄加权平均值分别为(137.1±0.9)Ma(MSWD=0.56,n=24)和(136.8±1.2)Ma(MSWD=0.40,n=22);对矿区4件辉钼矿样品进行Re-Os定年,得到加权平均年龄为(136.5±1.0)Ma,等时线年龄为(136.1±2.3)Ma,在误差范围内成岩成矿时代一致,显示大湾锌钼矿床形成于早白垩世.大湾矿床中辉钼矿的w(Re)为5.816～16.484μg/g,反映了矿床成矿物质来源具有壳幔混合特征.区内流纹斑岩和蚀变体系为进一步找矿勘查的有利标志.  相似文献   

广州流溪河河水主要化学组成时空分布特征及控制因素   总被引：2，自引：0，他引：2  

徐谨立  王志兵  王希杰  韦刚健  谢露华  曾提 《地球化学》2021,50(2):211-218

本次研究报道了位于广州市典型热带-亚热带河流流溪河上游、中游和下游3个站点(东星、乌石和江高)河水的主要化学成分在近1年的持续变化时间序列.结果显示,3个站点河水的阳离子均主要来自硅酸盐的化学风化输出,但贡献率略有差异,其中在上游的东星站贡献率最大,下游的江高站次之,中游的乌石站相对较少.相较之下,阴离子的来源更为多样,其中F?主要来自于岩石风化,Cl?、SO42?和NO3?更多地受到海洋源降雨或咸潮作用的影响.流域内主要化学风化反应以钾长石、钠长石和钙长石的溶解为主.从上游到下游,Si/TZ+*比值和Si/(Na*+K)比值逐渐降低,说明上游硅酸盐岩风化较下游更为强烈.从上游到下游,随工农业生产活动的增加,人类活动对河流水化学组成的贡献逐渐增大,岩石风化输出的相对贡献逐渐减小.  相似文献   

柱色谱分离-分子筛络合洗脱过程中正构烷烃单体碳同位素分馏研究     

董浩伟  赵佳玉  曾凡刚  谢曼曼  尚文郁  王淑贤  孙青 《岩矿测试》2021,(3):349-357

应用气相色谱-气体同位素质谱(GC-C-IRMS)分析正构烷烃单体碳同位素之前,需要对饱和烃样品中正构烷烃和异构烷烃进行预分离、富集,在预分离和富集过程中正构烷烃单体碳同位素是否发生分馏是高精度分析正构烷烃单体碳同位素比值(δ~(13)C)的关键。本文以正构烷烃混合溶液为对象,利用柱色谱、5■分子筛络合、环己烷-正戊烷混合溶剂两次洗脱,GC-C-IRMS分析正构烷烃单体碳同位素,研究前处理过程中正构烷烃单体碳同位素是否发生分馏。结果表明:使用柱色谱分离前后,多数正构烷烃单体碳同位素比值相差-0.2‰～0.2‰;当5■分子筛不完全络合时,未络合的正构烷烃单体碳同位素比值偏重约0.7‰,可能发生了微弱的碳同位素分馏,但并未影响洗脱后的正构烷烃单体碳同位素比值;使用环己烷-正戊烷混合溶剂洗脱前后,碳同位素比值相差-0.2‰～0.5‰,以同样方式洗脱第二次,获得的正构烷烃单体碳同位素比值与模拟样品相差-0.3‰～0.2‰。分析不同回收率(20%)正构烷烃的单体碳同位素比值,处理前后的差值基本在0.3‰以内,可见当正构烷烃回收率低至20%左右时,其单体碳同位素仍未发生明显分馏。柱色谱分离-5■分子筛络合-混合溶剂洗脱方法适用于回收率大于20%的正构烷烃单体碳同位素分析。  相似文献